Penggunaan Koagulan Ganda dan Koagulan – Oksidator dalam Pengolahan Limbah Cair Industri Batik
DOI:
https://doi.org/10.47826/econews.4.2.p.39-44Keywords:
Batik wastewater treatment, dual coagulant, coagulant oxidizing agent, alum FeSO4, alum chlorineAbstract
Batik wastewater contains various chemical compounds, such as dyes, synthetic compounds, heavy metals, and organic compounds that can harm the environment. Therefore, proper waste management is required. The use of alum as coagulant in textile wastewater treatment is commonly used, but it is not effective enough to remove wastewater colour and reduce COD. This study aims to modify alum-based batik wastewater treatment using (i)double coagulant by combining alum - FeSO4; and (ii)coagulant-oxidizing agent with combination of alum – chlorine. This experimental study consisted of two stages, the first experiment aimed to determine the optimum composition dose of alum – FeSO4 and alum – chlorine in depositing waste pollutants, reducing the colour and pH of the effluent; the second experiment aims to determine the effect of alum - FeSO4 and alum - chlorine at the optimum dose in reducing the COD. The results showed that alum–chlorine in various compositions reduced colour ten times and precipitated pollutants two times better than alum-FeSO4. The optimum concentration ratio of alum:chlorine is 1:1 (1.2 g/L alum : 1.2 g/L chlorine). This dose reduced the pH to 8; depositing 0.385 g pollutants; removed 99.57% wastewater colour; and decreased COD from 686.9 mg/L to 235.53 mg/L
References
Aditya, D. F. (2014). Dampak Pengakuan Dunia terhadap Batik Indonesia pada Aspek Produksi di Kelurahan Kergon Kota Pekalongan. Fashion and Fashion Education Journal, 3(1), 27–32. https://doi.org/10.15294/ffej.v3i1.4430
Apriyani, N. (2018). Industri Batik: Kandungan Limbah Cair dan Metode Pengolahannya. Media Ilmiah Teknik Lingkungan, 3(1), 21–29.
Asharuddin, S. M., Othman, N., Zin, N. S. M., Tajarudin, H. A., Din, M. F. M., & Kumar, V. (2018). Performance assessment of cassava peel starch and alum as dual coagulant for turbidity removal in dam water. International Journal of Integrated Engineering, 10(4), 185–192. https://doi.org/10.30880/ijie.2018.10.04.029
Budiyanto, S., Anies, Purnaweni, H., & Sunoko, H. R. (2018). Environmental Analysis of the Impacts of Batik Waste Water Polution on the Quality of Dug Well Water in the Batik Industrial Center of Jenggot Pekalongan City. E3S Web of Conferences, 31. https://doi.org/10.1051/e3sconf/20183109008
Güneş, E., Demir, E., Güneş, Y., & Hanedar, A. (2019). Characterization and treatment alternatives of industrial container and drum cleaning wastewater: Comparison of Fenton-like process and combined coagulation/ oxidation processe. Separation Purification Technology, 209, 425–433. https://doi.org/10.1016/j.seppur.2018.07.060
Hakim, L. M. (2018). Batik Sebagai Warisan Budaya Bangsa dan Nation Brand Indonesia. Nation State: Journal of International Studies, 1(1), 61–90. https://doi.org/10.24076/NSJIS.2018v1i1.90
Herfiani, Z. H., Rezagama, A., & Nur, M. (2017). Pengolahan limbah cair zat warna jenis indigosol blue (C.I vat blue 4) sebagai hasil produksi kain batik menggunakan metode ozonasi dan adsorpsi arang aktif batok kelapa terhadap parameter COD dan warna. Jurnal Teknik Lingkungan, 5(3).
Jagaba, A. H., Abubakar, S., Lawal, I. M., Latiff, A. A. A., & Umaru, I. (2018). Wastewater Treatment Using Alum, the Combinations of Alum-Ferric Chloride, Alum-Chitosan, Alum-Zeolite and Alum- Moringa Oleifera as Adsorbent and Coagulant. International Journal of Engineering Management, 2(3), 67–75.
https://doi.org/10.11648/j.ijem.20180203.13
Khalik, W. F., Ho, L. N., & Ong. (2015). Decolorization and Mineralization of Batik Wastewater through Solar Photocatalytic Process. Sains Malaysiana, 44(4), 607–612. https://doi.org/10.17576/jsm-2015-4404-16
M.Yan, D., Wang, J., Qu, W., & He, C. W. K. (2007). Relative importance of hydrolyzed Al(III) species (Ala, Alb, and Alc) during coagulation with polyaluminum chloride: a case study with the typical micro-polluted source waters. J Colloid Interface, 316(2), 482–489. https://doi.org/10.1016/j.jcis.2007.08.036
Oladoja, N. A. (2015). Headway on natural polymeric coagulants in water and wastewater treatment operations. Journal of Water Process Engineering, 6, 174–192. ttps://doi.org/10.1016/j.jwpe.2015.04.004
Keputusan Presiden Republik Indonesia Nomor 33 Tahun 2009 tentang Hari Batik Nasional, (2009).
Ramayanti, D., & Ulil, A. (2019). Analisis Parameter COD (Chemical Oxygen Demand) dan pH (potential Hydrogen) Limbah Cair di PT. Pupuk Iskandar Muda (PT. PIM) Lhokseumawe. Quimica: Jurnal Kimia Sains dan Terapan, 1(1), 16–21.
Rana, S., & Suresh, S. (2017). Comparison of different Coagulants for Reduction of COD from Textile industry wastewater. Materials Today: Proceedings, 4(2), 567–574. https://doi.org/10.1016/j.matpr.2017.01.058
Şahinkaya, S. (2013). COD and color removal from synthetic textile wastewater by ultrasound assisted electro-Fenton oxidation process. Journal of Industrial and Engineering Chemistry, 19, 601–606.
https://doi.org/10.1016/j.jiec.2012.09.023
Siregar, A. P., Raya, A. B., Nugroho, A. D., Indana, F., Prasada, I. M. Y., Andiani, R., Simbolon, T. G. Y., & Kinasih, A. T. (2020). Upaya Pengembangan Industri Batik di Indonesia. Dinamika Kerajinan dan Batik: Majalah Ilmiah, 37(1), 79–92.
Solmaz, S. K. A., Birgu¨l, A., U¨ stu¨n, E., & Yonar, T. (2006). Colour and COD removal from textile effluent by coagulation and advanced oxidation processes. Coloration Technology, 122(2), 102–109.
https://doi.org/10.1111/j.1478-4408.2006.00016.x
Suliyanto, Novandari, W., & Setyawati, S. M. (2015). Persepsi Generasi Muda terhadap Profesi Pengrajin Batik Tulis di Purbalingga. Jurnal Ekonomi dan Bisnis, 18(1), 135–144. https://doi.org/10.24914/jeb.v18i1.275
Suryawan, I. W. K., Helmy, Q., & Notodarmojo, S. (2018). Textile wastewater treatment: colour and COD removal of reactive black- 5 by ozonation. The 4th International Seminar on Sustainable Urban Development. IOP Conference Series: Earth and Environmental Science. https://doi.org/10.1088/1755-1315/106/1/012102
Tatangindatu, F., Kalesaran, O., & Rompas, R. (2013). Studi Parameter Fisika Kimia Air pada Areal Budidaya Ikan di Danau Tondano, Desa Paleloan, Kabupaten Minahasa. Budidaya Perairan, 1(2), 8–19.
https://doi.org/10.35800/bdp.1.2.2013.1911
Wartiono, T., & Rosyida, A. (2009). Pemilihan tawas, ferri khlorida dan ferro sulfat sebagai zat koagulan yang paling efektif dalam pengolahan limbah cair tekstil. Jurnal Teknika ATW, 6(1).
Wibowo, E., Rokhmat, M., Yanto, D., & Murniati, R. (2017). Batik Wastewater Treatment Using TiO2 Nanoparticles Coated on the Surface of Plastic Sheet. Procedia Engineering, 170, 78–83.
https://doi.org/10.1016/j.proeng.2017.03.015
Yang, Z., Gao, B., & Yue, Q. (2010). Coagulation performance and residual aluminum speciation of Al2(SO4)3 and polyaluminum chloride (PAC) in Yellow River water treatment. Chemical Engineering Journal, 165(1), 122–132. https://doi.org/10.1016/j.cej.2010.08.076
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